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Applied Sciences OPEN ACCESS

Synthesis And Evaluation Of Metal-Doped Rice Husk Silica For Iodine Vapor Capture

Niyazova Dilnoza Bakhtiyorovna
Researcher (PhD), Institute of General and Inorganic Chemistry, ASc RUz, Tashkent, Uzbekistan
Mamajonov Bakhodirjon Madaminovich
Applicant (PhD Seeker), Namangan Institute of Engineering and Technology, Namangan, Uzbekistan
Khoshimov Shakhrom Mansurovich
Doctoral student (DSc), Institute of General and Inorganic Chemistry, ASc RUz, Tashkent, Uzbekistan
Abdikamalova Aziza Bakhtiyarovna
Chief researcher, Institute of General and Inorganic Chemistry, ASc RUz, Doctor of Chemical Sciences, Professor, Uzbekistan
Eshmetov Izzat Dusimbatovich
Chief researcher, Institute of General and Inorganic Chemistry, ASc RUz, Doctor of Chemical Sciences, Professor, Uzbekistan
Mamataliev Nozim Nimadjonovich
Chief researcher, Institute of General and Inorganic Chemistry, ASc RUz, Doctor of Chemical Sciences, Uzbekistan
Alisher Maksetbaevich Kalbaev
Junior Researcher, PhD, Institute of General and Inorganic Chemistry, ASc RUz, Tashkent, Republic of Uzbekistan, Uzbekistan
tajas 2025
VOL. 7 / NO. 11 NOVEMBER
VOLUME 7
ISSUE 11
YEAR 2025
PAGES 100-107

Abstract

Amorphous silica was synthesized from rice husk and doped with Ag, Cu, Zn, or Bi to develop iodine sorbents. The resulting metal-loaded silica materials, produced via thermal treatment after wet impregnation, were tested for iodine vapor uptake at 25 °C for 1 hour. Bismuth- and copper-modified silica achieved the highest capacities (0.5–0.6 g I2/g), outperforming silver (0.2 g/g) and zinc (0.15 g/g). The enhanced performance stems from chemisorption via metal iodide formation (AgI, CuI, ZnI2, BiI3). These results align with literature values and demonstrate a sustainable route to efficient iodine capture using low-cost rice husk silica combined with targeted metal additives.

Keywords

Rice husk silica iodine capture metal-doped sorbents

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